HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I)

HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I) - Names and Identifiers

Name	Hydridotetrakis(triphenylphosphine)rhodium(I)
Synonyms	HRh(PPh3)4 Hydridotetrakis(trip Hydrido tetra(triphenylphosphine)rhodium Hydridotetrakis(triphenylphosphine)rhodium Hydridotetrakis(triphenylphosphine)rhodium(Ⅰ) HYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I) Hydridotetrakis(triphenylphosphine)rhodium(I) Tetrakis(triphenylphosphine)rhodium(I) Hydride HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I) Carbbonyl hydridotris (triphenylphosphine)rhodium Hydridotetrakis(triphenylphosphine)rhodium(I) dec. 145-147C
CAS	18284-36-1
InChI	InChI=1/4C18H15P.Rh/c41-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h41-15H

HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I) - Physico-chemical Properties

Molecular Formula	C72H61P4Rh+
Molar Mass	1153.06
Melting Point	140-146°C(lit.)
Boling Point	360°C at 760 mmHg
Flash Point	181.7°C
Solubility	Soluble in chloroform, toluene
Vapor Presure	4.74E-05mmHg at 25°C
Appearance	Crystalline Powder
Color	Ochre
Storage Condition	under inert gas (nitrogen or Argon) at 2-8°C
Sensitive	Air Sensitive
MDL	MFCD00015867

HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I) - Risk and Safety

Hazard Symbols	Xi - Irritant
Risk Codes	36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 - Wear suitable gloves and eye/face protection
WGK Germany	3
TSCA	No
HS Code	28439090

HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I) - Introduction

Hydridotrakis (triphenylphosphine)rhodium(I), also known as tetrakis(triphenylphosphine)rhodium(I) chloride, chemical formula [RhCl(PPh3)4], is an organometallic compound. The following is a description of the properties, uses, preparation and safety information of the compound:

Nature:
1. Hydridotetrakis(triphenylphosphine)rhodium(I) is a colorless crystal, soluble in organic solvents.
2. It is stable in the air, but may be hydrolyzed under acidic conditions.
3. The compound is a compound with tetrahedral coordination geometry, in which Rhodium and chloride ions are surrounded by triphenylphosphine ligands.

Use:
1. Hydridotetrakis(triphenylphosphine)rhodium(I) can be used as a catalyst to participate in a variety of organic synthesis reactions, such as hydrogenation, hydrogenated amination, hydrogenated aldehydes and ketones, and Swiss diazonium reactions.
2. It can also be used to prepare other Rhodium compounds as catalysts for various organic synthesis reactions.

Method:
Hydridotetrakis (triphenylphosphate) rhodium(I) can be prepared by the following steps:
First, the chlorine ligand of [RhCl3(H2O)3] is substituted with triphenylphosphine (PPh3) to obtain [RhCl(PPh3)3].
[RhCl(PPh3)3] is then reacted with sodium sulfite (Na2S2O4) to remove the last chloride ligand to give Hydridotetrakis (triphenylphosphate) rhodium(I).

Safety Information:
1. Hydridotetrakis (triphenylphosphate) rhodium(I) should be careful to avoid contact with skin and eyes and avoid inhaling dust or vapor during operation.
2. It should be stored in a sealed container, away from fire and oxidizing agents.
3. Use should wear protective gloves and glasses.
4. Dispose of waste properly after use and disposal, following local codes and regulations.

Last Update：2024-04-10 22:29:15